Kate Moss was all smiles at the Topshop Unique show at London Fashion Week, and maybe part of it is because of her upcoming TV appearance on E4. OK, we know it's a stretch, but go with it.

Moss, as we previously reported, is set to make an appearance on 'James' Salon', a documentary about the opening of her friend James Brown's first hair salon. "People will see how funny and warm and caring she is," Brown told WWD. "People will see the real her."

The one-hour documentary is set to air on Oct. 13 in the UK.